{"id":219,"date":"2015-07-22T00:10:08","date_gmt":"2015-07-22T00:10:08","guid":{"rendered":"http:\/\/www.kurzweilai.net\/?p=257121"},"modified":"2015-07-25T00:56:27","modified_gmt":"2015-07-25T00:56:27","slug":"korean-researchers-grow-wafer-scale-graphene-on-a-silicon-substrate","status":"publish","type":"post","link":"https:\/\/hoo.central12.com\/fugic\/2015\/07\/22\/korean-researchers-grow-wafer-scale-graphene-on-a-silicon-substrate\/","title":{"rendered":"Korean researchers grow wafer-scale graphene on a silicon substrate"},"content":{"rendered":"<div id=\"attachment_257123\" class=\"wp-caption aligncenter\" style=\"width: 443px;  border: 1px solid #dddddd; background-color: #f3f3f3; padding-top: 4px; margin: 10px; text-align:center; display: block; margin-right: auto; margin-left: auto;\"><a href=\"http:\/\/www.kurzweilai.net\/images\/carbon-ion-implantation.jpg\"><img class=\"size-full wp-image-257123 \" title=\"carbon ion implantation\" src=\"http:\/\/www.kurzweilai.net\/images\/carbon-ion-implantation.jpg\" alt=\"\" width=\"433\" height=\"355\" \/><\/a><p style=' padding: 0 4px 5px; margin: 0;'  class=\"wp-caption-text\">Wafer-scale (4 inch in diameter) synthesis of multi-layer graphene using high-temperature carbon ion implantation on nickel\/SiO2\/silicon (credit: J.Kim\/Korea University, Korea)<\/p><\/div>\n<p>Taking graphene a step closer to realistic commercial applications in silicon microelectronics,\u00a0<a href=\"http:\/\/korea.edu\/\" >Korea University<\/a> researchers have developed a simple microelectronics-compatible method for growing multi-layer graphene on a high-quality, wafer-scale (four inches in diameter) silicon substrate.<\/p>\n<p>The method is based on the ion implantation technique &#8212; a process in which ions are accelerated under an electrical field and smashed into a semiconductor. The impacting ions change the physical, chemical, or electrical properties of the semiconductor.<\/p>\n<p>Because of its high conductivity, &#8220;graphene is a potential contact electrode and an interconnection material linking semiconductor devices to form the desired electrical circuits, explained <a href=\"http:\/\/koreauniv.pure.elsevier.com\/en\/persons\/ji-hyun-kim(5028f3d5-180a-4637-a1cf-6dce1f1d8c99).html\" >Jihyun Kim<\/a>, the team leader and a professor in the Department of Chemical and Biological Engineering at Korea University.<\/p>\n<p>However, &#8220;to deposit large-area graphene that is free of wrinkles, tears, and residues on silicon wafers requires low temperatures. That can&#8217;t be achieved with conventional chemical vapor deposition, which requires a high growth temperature &#8212; above 1,000 degrees Celsius.&#8221; That can cause strains, metal spiking, cracks, wrinkles, and contaminants from diffusion of dopants.<\/p>\n<p>&#8220;Our synthesis method is controllable and scalable, allowing us to obtain graphene as large as the size of the silicon wafer,&#8221; Kim said. The researchers&#8217; next step is to further lower the temperature in the synthesis process and to control the thickness of the graphene for manufacturing production.<\/p>\n<p>The research is described in an <a href=\"http:\/\/scitation.aip.org\/content\/aip\/journal\/apl\/107\/3\/10.1063\/1.4926605\" >open-access paper<\/a> published this week in the<em>\u00a0<\/em>journal\u00a0<em>Applied Physics Letters.<\/em><\/p>\n<hr \/>\n<p><strong>Abstract of\u00a0<em>Wafer-scale synthesis of multi-layer graphene by high-temperature carbon ion implantation<\/em><\/strong><\/p>\n<p>We report on the synthesis of wafer-scale (4\u2009in. in diameter) high-quality\u00a0multi-layer\u00a0graphene using high-temperature\u00a0carbon\u00a0ion implantation\u00a0on thin\u00a0Ni\u00a0films on a substrate of SiO2\/Si.Carbon\u00a0ions were bombarded at 20\u2009keV and a dose of 1\u2009\u00d7\u200910<sup>15\u2009<\/sup>cm<sup>\u22122<\/sup>\u00a0onto the surface of the Ni\/SiO2\/Si substrate at a\u00a0temperature\u00a0of 500\u2009\u00b0C. This was followed by high-temperature activation annealing (600\u2013900\u2009\u00b0C) to form a sp<sup>2<\/sup>-bonded honeycomb structure. The effects of post-implantation activation annealing conditions were systematically investigated by micro-Raman spectroscopy and\u00a0transmission electron microscopy.\u00a0Carbon\u00a0ion implantation\u00a0at elevated\u00a0temperatures\u00a0allowed a lower activation annealing\u00a0temperature\u00a0for fabricating large-area\u00a0graphene.\u00a0Our results indicate that carbon-ion\u00a0implantation\u00a0provides a facile and direct route for integrating\u00a0graphene\u00a0with Si microelectronics.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Taking graphene a step closer to realistic commercial applications in silicon microelectronics,&nbsp;Korea University researchers have developed a simple microelectronics-compatible method for growing multi-layer graphene on a high-quality, wafer-scale (four inches in diameter) silicon substrate. The method is based on the ion implantation technique &mdash; a process in which ions are accelerated under an electrical field [&#8230;]<\/p>\n","protected":false},"author":13,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[48,43],"tags":[],"class_list":["post-219","post","type-post","status-publish","format-standard","hentry","category-electronics","category-news"],"_links":{"self":[{"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/posts\/219"}],"collection":[{"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/users\/13"}],"replies":[{"embeddable":true,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/comments?post=219"}],"version-history":[{"count":1,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/posts\/219\/revisions"}],"predecessor-version":[{"id":220,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/posts\/219\/revisions\/220"}],"wp:attachment":[{"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/media?parent=219"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/categories?post=219"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/hoo.central12.com\/fugic\/wp-json\/wp\/v2\/tags?post=219"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}